Volume 624
Main Index

Issues 1-2, Pages 1-406 (1 April 2001)

Preface Pages 1-3 Ilan Marek

Carbon nucleophile addition to sp2-unsaturated Fischer carbene complexes Pages 5-17 José Barluenga, Josefa Flórez, Francisco J. Fañanás

Contra-intuitive stereocontrol: endo-selective nucleophilic additions on an arene–tricarbonylchromium template Pages 18-25 Amitabha Sarkar, Sambasivam Ganesh, Surojit Sur, Sunil K. Mandal, Vishwanath M. Swamy, Bikash C. Maity, Tipparaju Suresh Kumar

Addition–β-elimination: a new method for the preparation of organometallic compounds Pages 26-33 Annie Liard, Julia Kaftanov, Helena Chechik, Shahera Farhat, Natalia Morlender-Vais, Claudia Averbuj, Ilan Marek

Studies on regioselective addition of benzylic organometallics to α-oxoketene dithioacetals in our aromatic annelation protocol Pages 34-40 H. Ila*, H. Junjappa*, O. Barun

On the evolution of organozinc carbenoid chemistry from carbonyl compounds — a personal account Pages 41-46 William B. Motherwell

Oxidation of organometallic compounds (RM, M=Li, MgBr, ZnBr, CuCNLi, Cu(R)CNLi2) with tBuOOLi, Ti(OiPr)4- mediated with tBuOOH, and with O2, to give alcohols (ROH). Are radicals R√ involved? Pages 47-52 Michael Möller, Marc Husemann, Gernot Boche

Generation of allylic and benzylic organolithium compounds by fluorine–lithium exchange: reaction with electrophiles Pages 53-57 David Guijarro, Miguel Yus

A single-strand polymer of hexacoordinated zinc(II) phosphodiester complex Pages 58-62 Ariane Angeloff, Jean-Claude Daran*, Jean Bernadou*, Bernard Meunier

W(CO)6-Mediated desulfuroligomerization of bis-dithioacetals. New synthesis of substituted oligo(phenylene–vinylenes) Pages 63-68 Chung-Wai Shiau, Clifton K. F. Shen, Wei Pan, Chi-Hong Kuo, Shen Chung Kao, Tien-Yau Luh

Silyl-cupration of a propargylsilane as a test for the reversibility of a metallo-metallation Pages 69-72 Maria Angeles Cubillo de Dios, Ian Fleming, Wibke Friedhoff, Philip D. W. Woode

The rhodium-catalyzed Pauson–Khand reaction Pages 73-87 Toshitake Kobayashi, Yuji Koga, Koichi Narasaka

New preparation of benzylic zinc reagents via a fragmentation reaction Pages 88-95 Claudia Piazza, Nicolas Millot, Paul Knochel

Synthesis of enantioenriched indene-derived bicyclic alcohols and tricyclic cyclopropanes via (−)-sparteine-mediated lithiation of a racemic precursor and kinetic resolution during the cyclocarbolithiation Pages 96-104 H. Laqua, R. Fröhlich, B. Wibbeling, D. Hoppe

A new approach to β-functional phospholes. Application to the synthesis of a β-CH2---CH2-bridged diphosphole disulphide Pages 105-109 Bernard Deschamps, François-Xavier Buzin, Adina Avarvari, François Nief, François Mathey

Synthesis and structure analysis of tricarbonyl[tetrakis(1′-methylcyclopropyl)cyclobutadiene]iron(0) Pages 110-113 Ingo Emme, Thomas Labahn, Armin de Meijere

Weakly ligated palladium complexes PdCl2(RCN)2 in piperidine: versatile catalysts for Sonogashira reaction of vinyl chlorides at room temperature Pages 114-123 Mouâd Alami, Benoit Crousse, Fabiola Ferri

Bimetallic π-conjugated complexes modulated by a carbonyl spacer: synthesis of arenetricarbonylchromium–ferrocene derivatives Pages 124-130 Damien Prim, Audrey Auffrant, Zoi F. Plyta, Jean-Philippe Tranchier, Françoise Rose-Munch, Eric Rose

Iron catalyzed hydrodebromination of 2-aryl-1,1-dibromo-1-alkenes Pages 131-135 Mohamed Akram Fakhfakh, Xavier Franck, Reynald Hocquemiller, Bruno Figadère

Highly diastereoselective desymmetrizing intramolecular cyclization of allylstannane with a diketone promoted by Lewis acid or transition metal complex Pages 136-142 Takashi Shimada, Naoki Asao, Yoshinori Yamamoto

Regioselective alkylzirconation of internal alkynes Pages 143-150 Shigeo Yamanoi, Kentaro Seki, Takashi Matsumoto, Keisuke Suzuki

A highly efficient and practical preparation of 2,4-pentadienyltitaniums and their γ-selective addition reaction with aldehydes and ketones Pages 151-156 Sentaro Okamoto, Fumie Sato

Synthesis of novel 1,1′-bis(oxazolinyl)metallocenes and their application in the asymmetric phenyl transfer from organozincs to aldehydes Pages 157-161 C. Bolm, N. Hermanns, M. Kesselgruber, J. P. Hildebrand

Chiral 1,2-bis(phosphetano)ethanes Pages 162-166 Angela Marinetti, Sébastien Jus, Jean-Pierre Genêt, Louis Ricard

Alkylation of nitroarenes with Grignard reagents via oxidative nucleophilic substitution of hydrogen Pages 167-171 Mieczysaw Mkosza, Marek Surowiec

Organotransition metal modified sugars: Part 22. Direct metalation of glycals: short and efficient routes to diversely protected stannylated glycals Pages 172-185 Christoph Jäkel, Karl Heinz Dötz

Transition-metal catalyzed synthesis of δ-hydroxy-γ-lactones from bis(trimethylsilyl) ketene acetals and allylic acetates via γ-unsaturated carboxylic acids. Comments on the formation of α-cyclopropyl carboxylic acids Pages 186-202 Henri Rudler, Paul Harris, Andrée Parlier, Frédéric Cantagrel, Bernard Denise, Moncef Bellassoued, Jacqueline Vaissermann

Controlled monohalogenation of phosphonates: Part IV. Selective synthesis of monohalogenomethylenediphosphonates Pages 203-207 Bogdan Iorga, Philippe Savignac

Solid phase cross-coupling reaction of aryl(halo)silanes with 4-iodobenzoic acid Pages 208-216 Fadi Homsi, Kazushi Hosoi, Kyoko Nozaki, Tamejiro Hiyama

Rate and mechanism of the reversible formation of a cationic (η3-allyl)palladium(II) complex in the oxidative addition of allylic acetate to a palladium(0) complex ligated by diop: an unusual behavior Pages 217-222 Christian Amatore, Sophie Gamez, Anny Jutand*

Stereoselective addition of organomanganese reagents to chiral acylsilanes and aldehydes Pages 223-228 Céline Boucley, Gérard Cahiez, Silvia Carini, Vanda Cerè, Mauro Comes-Franchini, Paul Knochel, Salvatore Pollicino, Alfredo Ricci

Carbon–carbon bond formation via oxidative-addition processes of titanium(II) reagents with π-bonded organic substrates. Reactivity modifications by Lewis acids and Lewis bases: Part 22. Organic chemistry of subvalent transition metal complexes Pages 229-238 John J. Eisch, John N. Gitua, Peter O. Otieno, Xian Shi

Asymmetric allylboration for the synthesis of β-hydroxy-δ-lactone unit of statin drug analogs Pages 239-243 M. Venkat Ram Reddy, Herbert C. Brown*, P. Veeraraghavan Ramachandran*

Palladium catalyzed cyclization reactions of acetylenic lactams Pages 244-258 Willem F. J. Karstens, Marianne Stol, Floris P. J. T. Rutjes, Huub Kooijman, Anthony L. Spek, Henk Hiemstra

Rhodium-catalysed asymmetric ring opening of oxabicyclic alkenes with heteroatom nucleophiles Pages 259-270 Mark Lautens, Keith Fagnou, Mark Taylor, Tomislav Rovis

Chiral platinum and palladium complexes containing functionalized C2-symmetric bisaminoaryl ‘Pincer’ ligands Pages 271-286 Martin Albrecht, Betty M. Kocks, Anthony L. Spek*, Gerard van Koten*

Synthesis and characterization of organotin triflate clusters Pages 287-293 Akihiro Orita, Jiannan Xiang, Katsumasa Sakamoto, Junzo Otera

The BF3 and B(C6F5)3-catalyzed 1,3-isomerization of allylic stannanes Pages 294-299 James A. Marshall, Kevin Gill

Synthesis of substituted cyclopropanone acetals by carbometallation and its oxidative cleavage with manganese(IV) oxide and lead(IV) oxide Pages 300-306 Masaharu Nakamura, Toshihiro Inoue, Eiichi Nakamura

Reactivity of lithium diphenylphosphonium diylides towards phosphorus electrophiles: Synthesis of α,β-unsaturated phosphorus compounds Pages 307-315 Marc Taillefer*, Henri Jean Cristau*, Alain Fruchier, Virginie Vicente

A short synthesis of (−)-dendrobine. Some observations on the nickel mediated radical cyclisation and on the Pauson–Khand reaction Pages 316-326 Jérôme Cassayre*, Samir Z. Zard*

Cross-metathesis reaction. Generation of highly functionalized olefins from unsaturated alcohols Pages 327-332 Janine Cossy, Samir BouzBouz, Amir H. Hoveyda

Direct use of chiral or achiral organophosphorus boranes as pro-ligands for transition metal catalyzed reactions Pages 333-343 Christophe Darcel, El Bachir Kaloun, Rachid Merdès, Dominique Moulin, Nadège Riegel, Serge Thorimbert, Jean Pierre Genêt, Sylvain Jugé

Neutral, non-racemising, catalytic aerobic oxidation of alcohols Pages 344-347 István E. Markó, Arnaud Gautier, Jean-Luc Mutonkole, Raphaël Dumeunier, Ali Ates, Christopher J. Urch, Stephen M. Brown

Nickel-catalysed three-component connection reaction of a phenyl group, conjugated dienes, and aldehydes: stereoselective synthesis of (E)-5-phenyl-3-penten-1-ols and (E)-3-methyl-5-phenyl-3-penten-1-ols Pages 348-353 Kazufumi Shibata, Masanari Kimura, Keisuke Kojima, Shuji Tanaka, Yoshinao Tamaru

Self-organization of a rigid α,ω-bis-silanediol determined by X-ray crystal structure Pages 354-358 Francis Carré, Geneviève Cerveau, Robert J. P. Corriu*, Bertrand Dabiens

Synthesis of (−)-coniine and (−)-pipecoline using ruthenium catalyzed ring closing metathesis Pages 359-363 Kandasamy Pachamuthu, Yashwant D. Vankar

On the steric course of transmetallations on enantiomerically defined α-carbamoyloxy organolithiums Pages 364-366 Katsuhiko Tomooka, Hideo Shimizu, Takeshi Nakai

Hydrosilylation of aldehydes and ketones catalyzed by [Ph3P(CuH)]6 Pages 367-371 Bruce H. Lipshutz, Will Chrisman, Kevin Noson

Cross-coupling of vinylpolysiloxanes with aryl iodides Pages 372-375 Scott E. Denmark, Zhigang Wang

Versatile palladium-catalyzed arylation of organomanganese chlorides by aryl bromides Pages 376-379 Eric Riguet, Mouâd Alami, Gérard Cahiez

1,4-Bis(arylsulfonyl)dihydropyridines in synthesis. Enantioselective synthesis of 2,3,6-trisubstituted piperidines Pages 380-382 Santiago Carballares, Donald Craig

Reactivity of γ-benzyloxyallyltins with cyclohexylidene glyceraldehydes Pages 383-387 Florian Fliegel, Isabelle Beaudet, Jean-Paul Quintard

TRISPHAT salts. Efficient NMR chiral shift and resolving agents for substituted cyclometallated ruthenium bis(diimine) complexes Pages 388-391 David Monchaud, Jérôme Lacour*, Christophe Coudret*, Sandrine Fraysse

Scandium perfluoroalkanesulfonate-catalyzed Diels–Alder reactions in an organic solvent Pages 392-394 Sh Kobayashi, Takehiro Tsuchiya, Ichiro Komoto, Jun-ichi Matsuo

Author Index Pages 395-396

Subject Index Pages 397-403

Contents to Volume 624 Pages 404-406